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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">geomorf</journal-id><journal-title-group><journal-title xml:lang="ru">Геоморфология и палеогеография</journal-title><trans-title-group xml:lang="en"><trans-title>Geomorfologiya i Paleogeografiya</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2949-1789</issn><issn pub-type="epub">2949-1797</issn><publisher><publisher-name></publisher-name></publisher></journal-meta><article-meta><article-id custom-type="elpub" pub-id-type="custom">geomorf-3731</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Палеоэкология и динамика культуры в плейстоцене Евразии</subject></subj-group></article-categories><title-group><article-title>Источники вещества плейстоценовых отложений Денисовой пещеры (на примере южной галереи): практические алгоритмы интерпретации минералого-геохимической информации</article-title><trans-title-group xml:lang="en"><trans-title></trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Некипелова</surname><given-names>А. В.</given-names></name></name-alternatives><email xlink:type="simple">nekipelova@igm.nsc.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Сокол</surname><given-names>Э. В.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Козликин</surname><given-names>М. Б.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Шуньков</surname><given-names>М. В.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Филиппова</surname><given-names>К. А.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Хворов</surname><given-names>П. В.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Киселева</surname><given-names>Д. В.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-4"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Тихова</surname><given-names>В. Д.</given-names></name></name-alternatives><email xlink:type="simple">tikhova@nioch.nsc.ru</email><xref ref-type="aff" rid="aff-5"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Институт геологии и минералогии имени В. С. Соболева СО РАН, Институт археологии и этнографии СО РАН, Новосибирск</institution><country>Россия</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Институт археологии и этнографии СО РАН, Новосибирск</institution><country>Россия</country></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Южно-Уральский федеральный научный центр минералогии и геоэкологии УрО РАН, Ильменский заповедник, Миасс</institution><country>Россия</country></aff></aff-alternatives><aff-alternatives id="aff-4"><aff xml:lang="ru"><institution>Институт археологии и этнографии СО РАН, Новосибирск; Институт геологии и геохимии имени академика А. Н. Заварицкого УрО РАН, Екатеринбург</institution><country>Россия</country></aff></aff-alternatives><aff-alternatives id="aff-5"><aff xml:lang="ru"><institution>Новосибирский институт органической химии имени Н. Н. Ворожцова СО РАН, Новосибирск</institution><country>Россия</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2026</year></pub-date><pub-date pub-type="epub"><day>03</day><month>07</month><year>2026</year></pub-date><volume>57</volume><issue>2</issue><elocation-id>3731</elocation-id><permissions><copyright-statement>Copyright &amp;#x00A9; Некипелова А.В., Сокол Э.В., Козликин М.Б., Шуньков М.В., Филиппова К.А., Хворов П.В., Киселева Д.В., Тихова В.Д., 2026</copyright-statement><copyright-year>2026</copyright-year><copyright-holder xml:lang="ru">Некипелова А.В., Сокол Э.В., Козликин М.Б., Шуньков М.В., Филиппова К.А., Хворов П.В., Киселева Д.В., Тихова В.Д.</copyright-holder><copyright-holder xml:lang="en">Некипелова А.В., Сокол Э.В., Козликин М.Б., Шуньков М.В., Филиппова К.А., Хворов П.В., Киселева Д.В., Тихова В.Д.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://geomorphology.igras.ru/jour/article/view/3731">https://geomorphology.igras.ru/jour/article/view/3731</self-uri><abstract><p>Представлены результаты минералого-геохимического анализа реперных горизонтов плейстоценовых отложений в южной галерее Денисовой пещеры (Алтай, Россия). Их фазовый и химический составы охарактеризованы с использованием серии показателей: индексы химического выветривания CIA и ICV, соотношения макрокомпонентов (CaO/SiO2, P2O5/SiO2, Na2O/SiO2 и др.), микроэлементов (Sr/Ga, Na/Ga, Zn/Ga и др.), факторы обогащения (EFCa, EFNa, EFP, EFSr, EFZn, EFCu), а также количество индекс-минералов (кальцита, апатита, слюд, хлорита и кислого плагиоклаза). Изменение названных показателей с глубиной позволяет судить о смене источников поступления материала в пещерную полость и их вкладе на разных временных интервалах. Установлено, что зрелые продукты интенсивного химического выветривания сосредоточены только в древнейших археологически и палеонтологически стерильных отложениях слоя 19.2 (древнее MIS 9). Начиная с уровня слоя 19.1 (рубеж MIS 9–8), в отложениях появляются и затем постоянно присутствуют биогенные материалы (кости, копролиты, органическое вещество), а также незрелые продукты выветривания силикатных пород. Рост вклада биогенных материалов отчетливо прослеживается в интервале культуросодержащих слоев 18–13 (MIS 7-4), на что указывает согласованное увеличение концентраций биогенного апатита, фосфора и цинка в пещерных осадках. Впервые установлена природа аккумулированного в пещерных отложениях измельченного апатитового материала, и даны количественные оценки содержания апатитов, входящих в состав неизмененной костной ткани и копролитов хищников-остеофагов. Резкое обогащение отложений слоев 14 и 13 фосфором обусловлено скоплением в них копролитов гиен и отвечает интервалу максимальной биотической активности в южной галерее. В слоях 18 и 16.2 преобладает костный биоапатит. Его основными поставщиками в пещерные отложения были люди и/или хищники, не практикующие остеофагию. Подход, изложенный в работе, способен стать основой для создания универсального алгоритма аттестации отложений археологических и палеонтологических пещерных памятников с использованием минералого-геохимического инструментария.</p></abstract><kwd-group xml:lang="ru"><kwd>пещерная седиментация</kwd><kwd>осадочная летопись</kwd><kwd>геохимические и минералогические маркеры</kwd><kwd>палеолит</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Авторы глубоко признательны доктору Ю.В. Дублянскому (Институт геологии, Университет Леопольда Франценса, г. Инсбрук, Австрия) за интерес, проявленный к этой работе, консультации по вопросам спелеогенеза и плодотворную дискуссию. Мы также выражаем свою искреннюю благодарность анонимным рецензентам за высказанные замечания и полезные предложения по модернизации рукописи. Исследование выполнено за счет гранта Российского научного фонда № 24-78-10006, https://rscf.ru/project/24-78-10006</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Angelucci D.E., Anesin D., Martínez M.L. et al. (2013) Rethinking stratigraphy and site formation of the Pleistocene deposit at Cueva Negra del Estrecho del Río Quípar (Caravaca de la Cruz, Spain). Quat. Sci. Rev. Vol. No. 80. P. 195-199. https://doi.org/10.1016/j.quascirev.2013.09.009</mixed-citation><mixed-citation xml:lang="en">Angelucci D.E., Anesin D., Martínez M.L. et al. (2013) Rethinking stratigraphy and site formation of the Pleistocene deposit at Cueva Negra del Estrecho del Río Quípar (Caravaca de la Cruz, Spain). Quat. Sci. Rev. Vol. No. 80. P. 195-199. https://doi.org/10.1016/j.quascirev.2013.09.009</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Aranburu A., Arsuaga J.L., Sala N. (2017) The stratigraphy of the Sima de los Huesos (Atapuerca, Spain) and implications for the origin of the fossil hominin accumulation. Quat. Int. Vol. 433. P. 5-21. https://doi.org/10.1016/j.quaint.2015.02.044</mixed-citation><mixed-citation xml:lang="en">Aranburu A., Arsuaga J.L., Sala N. (2017) The stratigraphy of the Sima de los Huesos (Atapuerca, Spain) and implications for the origin of the fossil hominin accumulation. Quat. Int. Vol. 433. P. 5-21. https://doi.org/10.1016/j.quaint.2015.02.044</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Brown S., Wang N., Oertle A. et al. (2021). Zooarchaeology through the lens of collagen fingerprinting at Denisova Cave. Sci. Rep. Vol. 11. No. 1. 15457. https://doi.org/10.1038/s41598-021-94731-2</mixed-citation><mixed-citation xml:lang="en">Brown S., Wang N., Oertle A. et al. (2021). Zooarchaeology through the lens of collagen fingerprinting at Denisova Cave. Sci. Rep. Vol. 11. No. 1. 15457. https://doi.org/10.1038/s41598-021-94731-2</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Butler D.H., Dawson P.C. (2018) Untangling natural and anthropogenic multi‐element signatures in archaeological soils at the Ikirahak site, Arctic Canada. Boreas. Vol. 47. No. 1. P. 189-201. https://doi.org/10.1111/bor.12258</mixed-citation><mixed-citation xml:lang="en">Butler D.H., Dawson P.C. (2018) Untangling natural and anthropogenic multi‐element signatures in archaeological soils at the Ikirahak site, Arctic Canada. Boreas. Vol. 47. No. 1. P. 189-201. https://doi.org/10.1111/bor.12258</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Campaña I., Benito-Calvo A., Pérez-González A. et al. (2017) Pleistocene sedimentary facies of the Gran Dolina archaeo-paleoanthropological site (Sierra de Atapuerca, Burgos, Spain). Quat. Int. Vol. 433. P. 68-84. https://doi.org/10.1016/j.quaint.2015.04.023</mixed-citation><mixed-citation xml:lang="en">Campaña I., Benito-Calvo A., Pérez-González A. et al. (2017) Pleistocene sedimentary facies of the Gran Dolina archaeo-paleoanthropological site (Sierra de Atapuerca, Burgos, Spain). Quat. Int. Vol. 433. P. 68-84. https://doi.org/10.1016/j.quaint.2015.04.023</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Campaña I., Benito-Calvo A., Pérez-González A. et al. (2023) Reconstructing depositional environments through cave interior facies: The case of Galería Complex (Sierra de Atapuerca, Spain). Geomorphol. Vol. 440. 108864. https://doi.org/10.1016/j.geomorph.2023.108864</mixed-citation><mixed-citation xml:lang="en">Campaña I., Benito-Calvo A., Pérez-González A. et al. (2023) Reconstructing depositional environments through cave interior facies: The case of Galería Complex (Sierra de Atapuerca, Spain). Geomorphol. Vol. 440. 108864. https://doi.org/10.1016/j.geomorph.2023.108864</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Canti M., Huisman D.J. (2015) Scientific advances in geoarchaeology during the last twenty years. J. Archaeol. Sci. Vol. 56. P. 96-108 https://doi.org/10.1016/j.jas.2015.02.024</mixed-citation><mixed-citation xml:lang="en">Canti M., Huisman D.J. (2015) Scientific advances in geoarchaeology during the last twenty years. J. Archaeol. Sci. Vol. 56. P. 96-108 https://doi.org/10.1016/j.jas.2015.02.024</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Chernysheva E.V., Leonova E.V. (2016) Preliminary geochemical analysis results of the cultural deposits from Dvoynaya Cave in the Gubs Gorge. Brief communications of the Institute of Archaeology. No. 244. P. 340-354. (in Russ.)</mixed-citation><mixed-citation xml:lang="en">Chernysheva E.V., Leonova E.V. (2016) Preliminary geochemical analysis results of the cultural deposits from Dvoynaya Cave in the Gubs Gorge. Brief communications of the Institute of Archaeology. No. 244. P. 340-354. (in Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Cook D.E., Kovacevich B., Beach T. et al. (2006) Deciphering the inorganic chemical record of ancient human activity using ICP-MS: a reconnaissance study of late Classic soil floors at Cancuén, Guatemala. J. Archaeol. Sci. Vol. 33. No. 5. P. 628-640. https://doi.org/10.1016/j.jas.2005.09.019</mixed-citation><mixed-citation xml:lang="en">Cook D.E., Kovacevich B., Beach T. et al. (2006) Deciphering the inorganic chemical record of ancient human activity using ICP-MS: a reconnaissance study of late Classic soil floors at Cancuén, Guatemala. J. Archaeol. Sci. Vol. 33. No. 5. P. 628-640. https://doi.org/10.1016/j.jas.2005.09.019</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Cox R., Lowe D.R., Cullers R.L. (1995) The influence of sediment recycling and basement composition on evolution of mudrock chemistry in the southwestern United States. Geochim. Cosmochim. Acta. Vol. 59, No. 14. P. 2919-2940. https://doi.org/10.1016/0016-7037(95)00185-9.</mixed-citation><mixed-citation xml:lang="en">Cox R., Lowe D.R., Cullers R.L. (1995) The influence of sediment recycling and basement composition on evolution of mudrock chemistry in the southwestern United States. Geochim. Cosmochim. Acta. Vol. 59, No. 14. P. 2919-2940. https://doi.org/10.1016/0016-7037(95)00185-9.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Davidson D.A., Wilson C.A., Lemos I.S. et al. (2010) Tell formation processes as indicated from geoarchaeological and geochemical investigations at Xeropolis, Euboea, Greece. J. Archaeol. Sci. Vol. 37. No. 7. P. 1564-1571. https://doi.org/10.1016/j.jas.2010.01.017</mixed-citation><mixed-citation xml:lang="en">Davidson D.A., Wilson C.A., Lemos I.S. et al. (2010) Tell formation processes as indicated from geoarchaeological and geochemical investigations at Xeropolis, Euboea, Greece. J. Archaeol. Sci. Vol. 37. No. 7. P. 1564-1571. https://doi.org/10.1016/j.jas.2010.01.017</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Davis L.G., Macfarlan S.J., Henrickson C.N. (2012) A PXRF-based chemostratigraphy and provenience system for the Cooper’s Ferry site, Idaho. J. Archaeol. Sci. Vol. 39. No. 3. P. 663-671. https://doi.org/10.1016/j.jas.2011.10.029</mixed-citation><mixed-citation xml:lang="en">Davis L.G., Macfarlan S.J., Henrickson C.N. (2012) A PXRF-based chemostratigraphy and provenience system for the Cooper’s Ferry site, Idaho. J. Archaeol. Sci. Vol. 39. No. 3. P. 663-671. https://doi.org/10.1016/j.jas.2011.10.029</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Derevianko A.P., Molodin V.I. (1994). Denisova peshchera. Chast' 1 (Denisova Cave. Part 1). Novosibirsk: Nauka (Publ.). 260 p. (in Russ.)</mixed-citation><mixed-citation xml:lang="en">Derevianko A.P., Molodin V.I. (1994). Denisova peshchera. Chast' 1 (Denisova Cave. Part 1). Novosibirsk: Nauka (Publ.). 260 p. (in Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">D'Errico F., Villa P. (1997) Holes and grooves: the contribution of microscopy and taphonomy to the problem of art origins. J. Hum. Evol. Vol. 33. No. 1. P. 1-31.</mixed-citation><mixed-citation xml:lang="en">D'Errico F., Villa P. (1997) Holes and grooves: the contribution of microscopy and taphonomy to the problem of art origins. J. Hum. Evol. Vol. 33. No. 1. P. 1-31.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Elliott J.C. (2002) Calcium Phosphate Biominerals. Rev. Mineral Geochem. Vol. 48. No. 1. P. 427-453. https://doi.org/10.2138/rmg.2002.48.11</mixed-citation><mixed-citation xml:lang="en">Elliott J.C. (2002) Calcium Phosphate Biominerals. Rev. Mineral Geochem. Vol. 48. No. 1. P. 427-453. https://doi.org/10.2138/rmg.2002.48.11</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Farrant A.R., Smart P.L. (2011). Role of sediment in speleogenesis; sedimentation and paragenesis. Geomorphol. Vol. 134. No. (1-2). P. 79-93. https://doi.org/10.1016/j.geomorph.2011.06.006</mixed-citation><mixed-citation xml:lang="en">Farrant A.R., Smart P.L. (2011). Role of sediment in speleogenesis; sedimentation and paragenesis. Geomorphol. Vol. 134. No. (1-2). P. 79-93. https://doi.org/10.1016/j.geomorph.2011.06.006</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Finlayson C., Giles Pacheco F., Rodríguez-Vidal J. et al. (2006) Late survival of Neanderthals at the southernmost extreme of Europe. Nature. Vol. 443. No. 7113. P. 850-853. https://doi.org/10.1038/nature05195</mixed-citation><mixed-citation xml:lang="en">Finlayson C., Giles Pacheco F., Rodríguez-Vidal J. et al. (2006) Late survival of Neanderthals at the southernmost extreme of Europe. Nature. Vol. 443. No. 7113. P. 850-853. https://doi.org/10.1038/nature05195</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Fornós J.J., Gómez-Pujol L., Cifre J. et al. (2011) First steps in limestone weathering and erosion: an atomic force microscopy (AFM) and scanning electron microscopy (SEM) approach. Acta Carsol. Vol. 40. No. 2. P. 275-282. https://doi.org/10.3986/ac.v40i2.12</mixed-citation><mixed-citation xml:lang="en">Fornós J.J., Gómez-Pujol L., Cifre J. et al. (2011) First steps in limestone weathering and erosion: an atomic force microscopy (AFM) and scanning electron microscopy (SEM) approach. Acta Carsol. Vol. 40. No. 2. P. 275-282. https://doi.org/10.3986/ac.v40i2.12</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Frierdich A.J., Hasenmueller E.A., Catalano J.G. (2011) Composition and structure of nanocrystalline Fe and Mn oxide cave deposits: Implications for trace element mobility in karst systems. Chem. Geol. Vol. 284. No. 1-2. P. 82-96.</mixed-citation><mixed-citation xml:lang="en">Frierdich A.J., Hasenmueller E.A., Catalano J.G. (2011) Composition and structure of nanocrystalline Fe and Mn oxide cave deposits: Implications for trace element mobility in karst systems. Chem. Geol. Vol. 284. No. 1-2. P. 82-96.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Gallello G., Ramacciotti M., García‐Puchol O. et al. (2021) Analysis of stratigraphical sequences at Cocina Cave (Spain) using rare earth elements geochemistry. Boreas. Vol. 50. No. 4. P. 1190-1208. https://doi.org/10.1111/bor.12530</mixed-citation><mixed-citation xml:lang="en">Gallello G., Ramacciotti M., García‐Puchol O. et al. (2021) Analysis of stratigraphical sequences at Cocina Cave (Spain) using rare earth elements geochemistry. Boreas. Vol. 50. No. 4. P. 1190-1208. https://doi.org/10.1111/bor.12530</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Gao Y., Mucci A. (2003) Individual and competitive adsorption of phosphate and arsenate on goethite in artificial seawater. Chem. Geol. Vol. 199. No. 1-2. P. 91-109.</mixed-citation><mixed-citation xml:lang="en">Gao Y., Mucci A. (2003) Individual and competitive adsorption of phosphate and arsenate on goethite in artificial seawater. Chem. Geol. Vol. 199. No. 1-2. P. 91-109.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Gázquez F., Calaforra J.M., Rull F. (2012) Boxwork and ferromanganese coatings in hypogenic caves: an example from Sima de la Higuera Cave (Murcia, SE Spain). Geomorphol. No. 177. P. 158-166.</mixed-citation><mixed-citation xml:lang="en">Gázquez F., Calaforra J.M., Rull F. (2012) Boxwork and ferromanganese coatings in hypogenic caves: an example from Sima de la Higuera Cave (Murcia, SE Spain). Geomorphol. No. 177. P. 158-166.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Ghinassi M., Colonese A. C., Giuseppe Z.D. et al. (2009) The Late Pleistocene clastic deposits in the Romito Cave, southern Italy: a proxy record of environmental changes and human presence. J. Quat. Sci. Vol. 24. P. 383-398. https://doi.org/10.1002/jqs.1236</mixed-citation><mixed-citation xml:lang="en">Ghinassi M., Colonese A. C., Giuseppe Z.D. et al. (2009) The Late Pleistocene clastic deposits in the Romito Cave, southern Italy: a proxy record of environmental changes and human presence. J. Quat. Sci. Vol. 24. P. 383-398. https://doi.org/10.1002/jqs.1236</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Greaney A.T., Rudnick R.L., Gaschnig R.M. et al. (2018) Geochemistry of molybdenum in the continental crust. Geochim. Cosmochim. Acta. No. 238. P. 36-54. https://doi.org/10.1016/j.gca.2018.06.039</mixed-citation><mixed-citation xml:lang="en">Greaney A.T., Rudnick R.L., Gaschnig R.M. et al. (2018) Geochemistry of molybdenum in the continental crust. Geochim. Cosmochim. Acta. No. 238. P. 36-54. https://doi.org/10.1016/j.gca.2018.06.039</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Gryczewska N., Sulwiński M., Chibowski P. et al. (2025). Applying sterols and bile acids as biomarkers for identifying human versus wild animals' faecal traces in cave sediments at archaeological sites. Archaeometry. No. 181. 106311. https://doi.org/10.1016/j.jas.2025.106311</mixed-citation><mixed-citation xml:lang="en">Gryczewska N., Sulwiński M., Chibowski P. et al. (2025). Applying sterols and bile acids as biomarkers for identifying human versus wild animals' faecal traces in cave sediments at archaeological sites. Archaeometry. No. 181. 106311. https://doi.org/10.1016/j.jas.2025.106311</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Homsey L.K., Capo R.C. (2006) Integrating geochemistry and micromorphology to interpret feature use at Dust Cave, a Paleo‐Indian through middle‐archaic site in Northwest Alabama. Geoarchaeol. Int. J. Vol. 21. No. 3. P. 237-269. https://doi.org/10.1002/gea.20103</mixed-citation><mixed-citation xml:lang="en">Homsey L.K., Capo R.C. (2006) Integrating geochemistry and micromorphology to interpret feature use at Dust Cave, a Paleo‐Indian through middle‐archaic site in Northwest Alabama. Geoarchaeol. Int. J. Vol. 21. No. 3. P. 237-269. https://doi.org/10.1002/gea.20103</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Hunt C., Davison J., Inglis R. et al. (2010) Site formation processes in caves: the Holocene sediments of the Haua Fteah, Cyrenaica, Libya. J. Archaeol. Sci. Vol. 37. No. 7. P. 1600-1611. https://doi.org/10.1016/j.jas.2010.01.021</mixed-citation><mixed-citation xml:lang="en">Hunt C., Davison J., Inglis R. et al. (2010) Site formation processes in caves: the Holocene sediments of the Haua Fteah, Cyrenaica, Libya. J. Archaeol. Sci. Vol. 37. No. 7. P. 1600-1611. https://doi.org/10.1016/j.jas.2010.01.021</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Interpretatsiya geokhimicheskikh dannykh (Interpretation of geochemistry data). (2001) Sklyarov E.V., Gladkochub D.P., Donskaya T.V., Ivanov A.V., Letnikova E.F., Mironov A.G., Barash I.G., Bulanov V.A., Sizykh A.I. Moscow: Intermet Engineering (Publ.). 228 p. (in Russ.)</mixed-citation><mixed-citation xml:lang="en">Interpretatsiya geokhimicheskikh dannykh (Interpretation of geochemistry data). (2001) Sklyarov E.V., Gladkochub D.P., Donskaya T.V., Ivanov A.V., Letnikova E.F., Mironov A.G., Barash I.G., Bulanov V.A., Sizykh A.I. Moscow: Intermet Engineering (Publ.). 228 p. (in Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Jacobs Z., Li B., Shunkov M.V. et al. (2019) Timing of archaic hominin occupation of Denisova Cave in southern Siberia. Nature. Vol. 565. No. 7741. P. 594-599. https://doi.org/10.1038/s41586-018-0843-2</mixed-citation><mixed-citation xml:lang="en">Jacobs Z., Li B., Shunkov M.V. et al. (2019) Timing of archaic hominin occupation of Denisova Cave in southern Siberia. Nature. Vol. 565. No. 7741. P. 594-599. https://doi.org/10.1038/s41586-018-0843-2</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Jacobs Z., Zavala E.I., Li B. et al. (2025) Pleistocene chronology and history of hominins and fauna at Denisova Cave. Nature Com. Vol. 16. No. 1. P. 4738. https://doi.org/10.1038/s41467-025-60140-6</mixed-citation><mixed-citation xml:lang="en">Jacobs Z., Zavala E.I., Li B. et al. (2025) Pleistocene chronology and history of hominins and fauna at Denisova Cave. Nature Com. Vol. 16. No. 1. P. 4738. https://doi.org/10.1038/s41467-025-60140-6</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">Jones D.S., Northup D.E. (2021). Cave decorating with microbes: Geomicrobiology of caves. Elements. Vol. 17. No. 2. P. 107-112.</mixed-citation><mixed-citation xml:lang="en">Jones D.S., Northup D.E. (2021). Cave decorating with microbes: Geomicrobiology of caves. Elements. Vol. 17. No. 2. P. 107-112.</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Jordá Pardo J.F., Álvarez-Alonso D., de Andrés-Herrero M. et al. (2023) Geomorphology, Geoarchaeology, and Geochronology of the Upper Pleistocene Archaeological Site of El Olivo Cave (Llanera, Asturias, Northern Spain). Geosci. Vol. 13. No. 10. 301. https://doi.org/10.3390/geosciences13100301</mixed-citation><mixed-citation xml:lang="en">Jordá Pardo J.F., Álvarez-Alonso D., de Andrés-Herrero M. et al. (2023) Geomorphology, Geoarchaeology, and Geochronology of the Upper Pleistocene Archaeological Site of El Olivo Cave (Llanera, Asturias, Northern Spain). Geosci. Vol. 13. No. 10. 301. https://doi.org/10.3390/geosciences13100301</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Kanthilatha N., Boyd W., Chang N. (2017) Multi-element characterization of archaeological floors at the prehistoric archaeological sites at Ban Non Wat and Nong Hua Raet in Northeast Thailand. Quat. Int. Vol. 432. P. 66-78. https://doi.org/10.1016/j.quaint.2014.07.067</mixed-citation><mixed-citation xml:lang="en">Kanthilatha N., Boyd W., Chang N. (2017) Multi-element characterization of archaeological floors at the prehistoric archaeological sites at Ban Non Wat and Nong Hua Raet in Northeast Thailand. Quat. Int. Vol. 432. P. 66-78. https://doi.org/10.1016/j.quaint.2014.07.067</mixed-citation></citation-alternatives></ref><ref id="cit34"><label>34</label><citation-alternatives><mixed-citation xml:lang="ru">Karkanas P., Marean C., Bar-Matthews M. et al. (2021) Cave life histories of non-anthropogenic sediments help us understand associated archaeological contexts. Quat. Res. Vol. 99. P. 270-289. https://doi.org/10.1017/qua.2020.72</mixed-citation><mixed-citation xml:lang="en">Karkanas P., Marean C., Bar-Matthews M. et al. (2021) Cave life histories of non-anthropogenic sediments help us understand associated archaeological contexts. Quat. Res. Vol. 99. P. 270-289. https://doi.org/10.1017/qua.2020.72</mixed-citation></citation-alternatives></ref><ref id="cit35"><label>35</label><citation-alternatives><mixed-citation xml:lang="ru">Kehl M., Eckmeier E., Franz S.O. et al. (2014). Sediment sequence and site formation processes at the Arbreda Cave, NE Iberian Peninsula, and implications on human occupation and climate change during the Last Glacial. Climate of the Past. Vol. 10. No. 5. P. 1673-1692. https://doi.org/10.5194/cp-10-1673-2014</mixed-citation><mixed-citation xml:lang="en">Kehl M., Eckmeier E., Franz S.O. et al. (2014). Sediment sequence and site formation processes at the Arbreda Cave, NE Iberian Peninsula, and implications on human occupation and climate change during the Last Glacial. Climate of the Past. Vol. 10. No. 5. P. 1673-1692. https://doi.org/10.5194/cp-10-1673-2014</mixed-citation></citation-alternatives></ref><ref id="cit36"><label>36</label><citation-alternatives><mixed-citation xml:lang="ru">Kozlikin M.B. (2025) Srednij paleolit Altaya: kul'turnaya dinamika i prirodnaya sreda (The Middle Paleolithic of Altai: cultural dynamics and natural environment). PhD thesis. Novosibirsk: IAET SB RAS (Publ.). 344 p. (in Russ.).</mixed-citation><mixed-citation xml:lang="en">Kozlikin M.B. (2025) Srednij paleolit Altaya: kul'turnaya dinamika i prirodnaya sreda (The Middle Paleolithic of Altai: cultural dynamics and natural environment). PhD thesis. Novosibirsk: IAET SB RAS (Publ.). 344 p. (in Russ.).</mixed-citation></citation-alternatives></ref><ref id="cit37"><label>37</label><citation-alternatives><mixed-citation xml:lang="ru">Kulik N.A., Deev E.V., Ulianov V.A. et al. (2023). Manifestations of neotectonics in karst cavities: identification experience on the example of Denisova Cave in Gorny Altai. Teoriya i praktika arheologicheskih issledovanij. Vol. 35. No. 4. P. 193–211. (in Russ.). https://doi.org/10.14258/tpai(2023)35(4).-11</mixed-citation><mixed-citation xml:lang="en">Kulik N.A., Deev E.V., Ulianov V.A. et al. (2023). Manifestations of neotectonics in karst cavities: identification experience on the example of Denisova Cave in Gorny Altai. Teoriya i praktika arheologicheskih issledovanij. Vol. 35. No. 4. P. 193–211. (in Russ.). https://doi.org/10.14258/tpai(2023)35(4).-11</mixed-citation></citation-alternatives></ref><ref id="cit38"><label>38</label><citation-alternatives><mixed-citation xml:lang="ru">Kulkova T.F., Lyubin V.P. (1980) The sediments study results of the Kudaro I and Kudaro III caves using the phosphate analysis method. In: Kudarskie peshchernye paleoliticheskie stojanki v Jugo-Osetii (voprosy stratigrafii, jekologii, hronologii). Moscow: Nauka (Publ.). P. 45–50. (in Russ.)</mixed-citation><mixed-citation xml:lang="en">Kulkova T.F., Lyubin V.P. (1980) The sediments study results of the Kudaro I and Kudaro III caves using the phosphate analysis method. In: Kudarskie peshchernye paleoliticheskie stojanki v Jugo-Osetii (voprosy stratigrafii, jekologii, hronologii). Moscow: Nauka (Publ.). P. 45–50. (in Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit39"><label>39</label><citation-alternatives><mixed-citation xml:lang="ru">Langford B., Vaks A., Kutuzov I. et al. (2025). From hypogenic to biogenic speleogenesis in semi-arid climate: Bat guano-driven carbonate weathering and cave modification in Chariton Cave, Israel. Geomorphol. 109815. https://doi.org/10.1016/j.geomorph.2025.109815</mixed-citation><mixed-citation xml:lang="en">Langford B., Vaks A., Kutuzov I. et al. (2025). From hypogenic to biogenic speleogenesis in semi-arid climate: Bat guano-driven carbonate weathering and cave modification in Chariton Cave, Israel. Geomorphol. 109815. https://doi.org/10.1016/j.geomorph.2025.109815</mixed-citation></citation-alternatives></ref><ref id="cit40"><label>40</label><citation-alternatives><mixed-citation xml:lang="ru">Legros R., Balmain N., Bonel G. (1987) Age-related changes in mineral of rat and bovine cortical bone. Calcif. Tissue Int. Vol. 41. No. 3. P. 137-144. https://doi.org/10.1007/BF02563793</mixed-citation><mixed-citation xml:lang="en">Legros R., Balmain N., Bonel G. (1987) Age-related changes in mineral of rat and bovine cortical bone. Calcif. Tissue Int. Vol. 41. No. 3. P. 137-144. https://doi.org/10.1007/BF02563793</mixed-citation></citation-alternatives></ref><ref id="cit41"><label>41</label><citation-alternatives><mixed-citation xml:lang="ru">Lioubine V.P. (1998). The Acheulean epoch in the Caucasus. Saint Petersburg: Peterburgskoe vostokovedenie (Publ.). 192 p. (in Russ.)</mixed-citation><mixed-citation xml:lang="en">Lioubine V.P. (1998). The Acheulean epoch in the Caucasus. Saint Petersburg: Peterburgskoe vostokovedenie (Publ.). 192 p. (in Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit42"><label>42</label><citation-alternatives><mixed-citation xml:lang="ru">Madupalli H., Pavan B., Tecklenburg M.M.J. (2017) Carbonate substitution in the mineral component of bone: Discriminating the structural changes, simultaneously imposed by carbonate in A and B sites of apatite. J. Solid. State Chem. Vol. 255. P. 27-35. https://doi.org/10.1016/j.jssc.2017.07.025</mixed-citation><mixed-citation xml:lang="en">Madupalli H., Pavan B., Tecklenburg M.M.J. (2017) Carbonate substitution in the mineral component of bone: Discriminating the structural changes, simultaneously imposed by carbonate in A and B sites of apatite. J. Solid. State Chem. Vol. 255. P. 27-35. https://doi.org/10.1016/j.jssc.2017.07.025</mixed-citation></citation-alternatives></ref><ref id="cit43"><label>43</label><citation-alternatives><mixed-citation xml:lang="ru">Martini I., Ronchitelli A., Arrighi S. et al. (2018) Cave clastic sediments as a tool for refining the study of human occupation of prehistoric sites: insights from the cave site of La Cala (Cilento, southern Italy). J. Quat. Sci. Vol. 33. No. 5. P. 586-596.</mixed-citation><mixed-citation xml:lang="en">Martini I., Ronchitelli A., Arrighi S. et al. (2018) Cave clastic sediments as a tool for refining the study of human occupation of prehistoric sites: insights from the cave site of La Cala (Cilento, southern Italy). J. Quat. Sci. Vol. 33. No. 5. P. 586-596.</mixed-citation></citation-alternatives></ref><ref id="cit44"><label>44</label><citation-alternatives><mixed-citation xml:lang="ru">Marwick B. (2005) Element concentrations and magnetic susceptibility of anthrosols: indicators of prehistoric human occupation in the inland Pilbara, Western Australia. J. Archaeol. Sci. Vol. 32. No. 9. P. 1357-1368. https://doi.org/10.1016/j.jas.2005.03.009</mixed-citation><mixed-citation xml:lang="en">Marwick B. (2005) Element concentrations and magnetic susceptibility of anthrosols: indicators of prehistoric human occupation in the inland Pilbara, Western Australia. J. Archaeol. Sci. Vol. 32. No. 9. P. 1357-1368. https://doi.org/10.1016/j.jas.2005.03.009</mixed-citation></citation-alternatives></ref><ref id="cit45"><label>45</label><citation-alternatives><mixed-citation xml:lang="ru">McAdams C., Morley M.W., Fu X. et al. (2020) The Pleistocene geoarchaeology and geochronology of Con Moong Cave, North Vietnam: Site formation processes and hominin activity in the humid tropics. Geoarchaeol. Vol. 35. No. 1. P. 72-97. https://doi.org/10.1002/gea.21758</mixed-citation><mixed-citation xml:lang="en">McAdams C., Morley M.W., Fu X. et al. (2020) The Pleistocene geoarchaeology and geochronology of Con Moong Cave, North Vietnam: Site formation processes and hominin activity in the humid tropics. Geoarchaeol. Vol. 35. No. 1. P. 72-97. https://doi.org/10.1002/gea.21758</mixed-citation></citation-alternatives></ref><ref id="cit46"><label>46</label><citation-alternatives><mixed-citation xml:lang="ru">McElderry J.D.P., Zhu P., Mroue K. H. et al. (2013). Crystallinity and compositional changes in carbonated apatites: Evidence from 31P solid-state NMR, Raman, and AFM analysis. J. Solid State Chem. Vol. 206. P. 192-198. https://doi.org/10.1016/j.jssc.2013.08.011</mixed-citation><mixed-citation xml:lang="en">McElderry J.D.P., Zhu P., Mroue K. H. et al. (2013). Crystallinity and compositional changes in carbonated apatites: Evidence from 31P solid-state NMR, Raman, and AFM analysis. J. Solid State Chem. Vol. 206. P. 192-198. https://doi.org/10.1016/j.jssc.2013.08.011</mixed-citation></citation-alternatives></ref><ref id="cit47"><label>47</label><citation-alternatives><mixed-citation xml:lang="ru">McLennan S.M. (1993) Weathering and global denudation. J. Geol. Vol. 101. P. 295-303.</mixed-citation><mixed-citation xml:lang="en">McLennan S.M. (1993) Weathering and global denudation. J. Geol. Vol. 101. P. 295-303.</mixed-citation></citation-alternatives></ref><ref id="cit48"><label>48</label><citation-alternatives><mixed-citation xml:lang="ru">Misarti N., Finney B.P., Maschner H. (2011) Reconstructing site organization in the eastern Aleutian Islands, Alaska using multi-element chemical analysis of soils. J. Archaeol. Sci. Vol. 38. No. 7. P. 1441-1455. https://doi.org/10.1016/j.jas.2011.02.007</mixed-citation><mixed-citation xml:lang="en">Misarti N., Finney B.P., Maschner H. (2011) Reconstructing site organization in the eastern Aleutian Islands, Alaska using multi-element chemical analysis of soils. J. Archaeol. Sci. Vol. 38. No. 7. P. 1441-1455. https://doi.org/10.1016/j.jas.2011.02.007</mixed-citation></citation-alternatives></ref><ref id="cit49"><label>49</label><citation-alternatives><mixed-citation xml:lang="ru">Monge G., Jimenez-Espejo F.J., García-Alix A. et al. (2015) Earliest evidence of pollution by heavy metals in archaeological sites. Sci. Rep. Vol. 5. No. 1. P. 14252. https://doi.org/10.1038/srep14252</mixed-citation><mixed-citation xml:lang="en">Monge G., Jimenez-Espejo F.J., García-Alix A. et al. (2015) Earliest evidence of pollution by heavy metals in archaeological sites. Sci. Rep. Vol. 5. No. 1. P. 14252. https://doi.org/10.1038/srep14252</mixed-citation></citation-alternatives></ref><ref id="cit50"><label>50</label><citation-alternatives><mixed-citation xml:lang="ru">Monge G., Jimenez-Espejo F.J., Pozo M. et al. (2016) A geochemical multi-proxy approach for anthropogenic processes in a Middle–Upper Pleistocene endokarstic deposit. Quat. Int. Vol. 407. P. 140-149. https://doi.org/10.1016/j.quaint.2016.02.004</mixed-citation><mixed-citation xml:lang="en">Monge G., Jimenez-Espejo F.J., Pozo M. et al. (2016) A geochemical multi-proxy approach for anthropogenic processes in a Middle–Upper Pleistocene endokarstic deposit. Quat. Int. Vol. 407. P. 140-149. https://doi.org/10.1016/j.quaint.2016.02.004</mixed-citation></citation-alternatives></ref><ref id="cit51"><label>51</label><citation-alternatives><mixed-citation xml:lang="ru">Morley M.V., Goldberg P., Uliyanov V. et al. (2019) Hominin and animal activities in the microstratigraphic record from Denisova Cave (Altai Mountains, Russia). Sci. Rep. Vol. 9. Article No. 13785. P. 1–12. https://doi.org/10.1038/s41598-019-49930-3</mixed-citation><mixed-citation xml:lang="en">Morley M.V., Goldberg P., Uliyanov V. et al. (2019) Hominin and animal activities in the microstratigraphic record from Denisova Cave (Altai Mountains, Russia). Sci. Rep. Vol. 9. Article No. 13785. P. 1–12. https://doi.org/10.1038/s41598-019-49930-3</mixed-citation></citation-alternatives></ref><ref id="cit52"><label>52</label><citation-alternatives><mixed-citation xml:lang="ru">Morrissey P., Wurz S., Ligouis B. et al. (2025) Burning, Cleaning, Dumping, and Dissolution: Site Formation Processes and Stratigraphy of Pre‐110,000‐Year‐Old MSA l Deposits in Cave 1, Klasies River Main Site, South Africa. Geoarchaeol. Vol. 40. No. 2. 70005. https://doi.org/10.1002/gea.70005</mixed-citation><mixed-citation xml:lang="en">Morrissey P., Wurz S., Ligouis B. et al. (2025) Burning, Cleaning, Dumping, and Dissolution: Site Formation Processes and Stratigraphy of Pre‐110,000‐Year‐Old MSA l Deposits in Cave 1, Klasies River Main Site, South Africa. Geoarchaeol. Vol. 40. No. 2. 70005. https://doi.org/10.1002/gea.70005</mixed-citation></citation-alternatives></ref><ref id="cit53"><label>53</label><citation-alternatives><mixed-citation xml:lang="ru">Nekipelova A.V., Sokol E.V., Kozlikin M.B. et al. (2024) Material Composition of Pleistocene Deposits in the South Chamber of Denisova Cave: First Results of Comparative Analysis. Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 30. P. 200-205 (in Russ.). https://doi.org/10.17746/2658-6193.2024.30.0200-0205</mixed-citation><mixed-citation xml:lang="en">Nekipelova A.V., Sokol E.V., Kozlikin M.B. et al. (2024) Material Composition of Pleistocene Deposits in the South Chamber of Denisova Cave: First Results of Comparative Analysis. Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 30. P. 200-205 (in Russ.). https://doi.org/10.17746/2658-6193.2024.30.0200-0205</mixed-citation></citation-alternatives></ref><ref id="cit54"><label>54</label><citation-alternatives><mixed-citation xml:lang="ru">Nesbitt H.W., Young G.M. (1982) Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature. Vol. 299. P. 715-717. https://doi.org/10.1038/299715a0</mixed-citation><mixed-citation xml:lang="en">Nesbitt H.W., Young G.M. (1982) Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature. Vol. 299. P. 715-717. https://doi.org/10.1038/299715a0</mixed-citation></citation-alternatives></ref><ref id="cit55"><label>55</label><citation-alternatives><mixed-citation xml:lang="ru">Prirodnaya sreda i chelovek v paleolite Gornogo Altaya (Paleoenvironment and Paleolithic human occupation of Gorny Altai) (2003). Derevianko A.P., Shunkov M.V., Agadjanian A.K. et al. Novosibirsk: IAET SB RAS (Publ.). 448 p. (in Russ.)</mixed-citation><mixed-citation xml:lang="en">Prirodnaya sreda i chelovek v paleolite Gornogo Altaya (Paleoenvironment and Paleolithic human occupation of Gorny Altai) (2003). Derevianko A.P., Shunkov M.V., Agadjanian A.K. et al. Novosibirsk: IAET SB RAS (Publ.). 448 p. (in Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit56"><label>56</label><citation-alternatives><mixed-citation xml:lang="ru">Rivals F., Baryshnikov G.F., Prilepskaya N.E. et al. (2022). Diet and ecological niches of the Late Pleistocene hyenas Crocuta spelaea and C. ultima ussurica based on a study of tooth microwear. Palaeogeograph. Palaeoclimatol. Palaeoecol. Vol. 601, 111125.</mixed-citation><mixed-citation xml:lang="en">Rivals F., Baryshnikov G.F., Prilepskaya N.E. et al. (2022). Diet and ecological niches of the Late Pleistocene hyenas Crocuta spelaea and C. ultima ussurica based on a study of tooth microwear. Palaeogeograph. Palaeoclimatol. Palaeoecol. Vol. 601, 111125.</mixed-citation></citation-alternatives></ref><ref id="cit57"><label>57</label><citation-alternatives><mixed-citation xml:lang="ru">Sennikov N.V., Obut O.T., Khabibulina R.A. et al. (2023). Reef complexes of the Late Ordovician–Early Silurian Altai Basin: classification, structure, paleobiota, and paleogeography. Russ. Geol. Geophys. Vol. 64. No. 3. P. 292-305. https://doi.org/10.2113/RGG20224458</mixed-citation><mixed-citation xml:lang="en">Sennikov N.V., Obut O.T., Khabibulina R.A. et al. (2023). Reef complexes of the Late Ordovician–Early Silurian Altai Basin: classification, structure, paleobiota, and paleogeography. Russ. Geol. Geophys. Vol. 64. No. 3. P. 292-305. https://doi.org/10.2113/RGG20224458</mixed-citation></citation-alternatives></ref><ref id="cit58"><label>58</label><citation-alternatives><mixed-citation xml:lang="ru">Shashkov M.V., Zhdanov A.A., Dedov I.E. et al. (2022). Organic and elemental Composition of Fire Residue in Surungur archaeological site with assessment fuel type used. Journal of Siberian Federal University. Chemistry. Vol. 15. No. 3. P. 365-376. (in Russ.). https://doi.org/10.17516/1998-2836-0300</mixed-citation><mixed-citation xml:lang="en">Shashkov M.V., Zhdanov A.A., Dedov I.E. et al. (2022). Organic and elemental Composition of Fire Residue in Surungur archaeological site with assessment fuel type used. Journal of Siberian Federal University. Chemistry. Vol. 15. No. 3. P. 365-376. (in Russ.). https://doi.org/10.17516/1998-2836-0300</mixed-citation></citation-alternatives></ref><ref id="cit59"><label>59</label><citation-alternatives><mixed-citation xml:lang="ru">Shunkov M.V., Kulik N.A., Kozlikin M.B. et al. (2018) The phosphates of Pleistocene–Holocene sediments of the Eastern Gallery of Denisova Cave. Doklady Earth Sciences. Vol. 478. P. 46-50. https://doi.org/10.1134/S1028334X18010270</mixed-citation><mixed-citation xml:lang="en">Shunkov M.V., Kulik N.A., Kozlikin M.B. et al. (2018) The phosphates of Pleistocene–Holocene sediments of the Eastern Gallery of Denisova Cave. Doklady Earth Sciences. Vol. 478. P. 46-50. https://doi.org/10.1134/S1028334X18010270</mixed-citation></citation-alternatives></ref><ref id="cit60"><label>60</label><citation-alternatives><mixed-citation xml:lang="ru">Shunkov M.V., Kozlikin M.B., Chekha A.M. et al. (2022) Paleolithic complexes of the South Chamber of Denisova Cave: 2022 materials. Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 28. P. 404-414 (in Russ.). https://doi.org/10.17746/2658-6193.2022.28.0407-0414</mixed-citation><mixed-citation xml:lang="en">Shunkov M.V., Kozlikin M.B., Chekha A.M. et al. (2022) Paleolithic complexes of the South Chamber of Denisova Cave: 2022 materials. Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 28. P. 404-414 (in Russ.). https://doi.org/10.17746/2658-6193.2022.28.0407-0414</mixed-citation></citation-alternatives></ref><ref id="cit61"><label>61</label><citation-alternatives><mixed-citation xml:lang="ru">Sokol E.V., Kozlikin M.B., Kokh S.N. et al. (2022) Phosphate record in pleistocene-holocene sediments from Denisova Cave: formation mechanisms and archaeological implications. Minerals. Vol. 12. No. 5. 553. https://doi.org/10.3390/min12050553</mixed-citation><mixed-citation xml:lang="en">Sokol E.V., Kozlikin M.B., Kokh S.N. et al. (2022) Phosphate record in pleistocene-holocene sediments from Denisova Cave: formation mechanisms and archaeological implications. Minerals. Vol. 12. No. 5. 553. https://doi.org/10.3390/min12050553</mixed-citation></citation-alternatives></ref><ref id="cit62"><label>62</label><citation-alternatives><mixed-citation xml:lang="ru">Sokol E.V., Nekipelova A.V., Kozlikin M.B. et al. (2024). The origin of biogenic horizons in the pleistocene strata of Denisova Cave: mineralogical and geochemical markers help to reconstruct the sources of matter. Archaeology, Ethnology &amp; Anthropology of Eurasia. Vol. 51. No. 1. P. 35–46. https://doi.org/10.17746/1563-0110.2024.52.1.035-046</mixed-citation><mixed-citation xml:lang="en">Sokol E.V., Nekipelova A.V., Kozlikin M.B. et al. (2024). The origin of biogenic horizons in the pleistocene strata of Denisova Cave: mineralogical and geochemical markers help to reconstruct the sources of matter. Archaeology, Ethnology &amp; Anthropology of Eurasia. Vol. 51. No. 1. P. 35–46. https://doi.org/10.17746/1563-0110.2024.52.1.035-046</mixed-citation></citation-alternatives></ref><ref id="cit63"><label>63</label><citation-alternatives><mixed-citation xml:lang="ru">Sokol E.V., Nekipelova A.V., Kozlikin M.B. et al. (2025) Geochemistry and mineralogy of sediments as tools for assessment of the cave biotic occupation: a case study of the Denisova Cave. Geomorfologiya i Paleogeografiya. Vol. 56. No. 3. P. 174-194. (in Russ.).</mixed-citation><mixed-citation xml:lang="en">Sokol E.V., Nekipelova A.V., Kozlikin M.B. et al. (2025) Geochemistry and mineralogy of sediments as tools for assessment of the cave biotic occupation: a case study of the Denisova Cave. Geomorfologiya i Paleogeografiya. Vol. 56. No. 3. P. 174-194. (in Russ.).</mixed-citation></citation-alternatives></ref><ref id="cit64"><label>64</label><citation-alternatives><mixed-citation xml:lang="ru">Springer G.S. (2019) Clastic sediments in caves. In: White W.B., Culver D.C., Pipan T. Encyclopedia of Caves. Elsevier Inc. P. 277-284. https://doi.org/10.1016/B978-0-12-814124-3.00031-5</mixed-citation><mixed-citation xml:lang="en">Springer G.S. (2019) Clastic sediments in caves. In: White W.B., Culver D.C., Pipan T. Encyclopedia of Caves. Elsevier Inc. P. 277-284. https://doi.org/10.1016/B978-0-12-814124-3.00031-5</mixed-citation></citation-alternatives></ref><ref id="cit65"><label>65</label><citation-alternatives><mixed-citation xml:lang="ru">Stancampiano L.M., Rubio-Jara S., Panera J. et al. (2023). Organic geochemical evidence of human-controlled fires at Acheulean site of Valdocarros II (Spain, 245 kya). Sci. Rep. Vol. 13. No. 1. 7119. https://doi.org/10.1038/s41598-023-32673-7</mixed-citation><mixed-citation xml:lang="en">Stancampiano L.M., Rubio-Jara S., Panera J. et al. (2023). Organic geochemical evidence of human-controlled fires at Acheulean site of Valdocarros II (Spain, 245 kya). Sci. Rep. Vol. 13. No. 1. 7119. https://doi.org/10.1038/s41598-023-32673-7</mixed-citation></citation-alternatives></ref><ref id="cit66"><label>66</label><citation-alternatives><mixed-citation xml:lang="ru">State Geological Map of the Russian Federation. Second edition. Scale 1:200,000. Ser. Altaisk. Sheet M-45-I (Soloneshnoe). Explanatory Note. FGUP Gorno-Altajskaya poiskovo-s"yomochnaya ekspediciya: Russia, 2001, Ed.: Shokalsky S.P.</mixed-citation><mixed-citation xml:lang="en">State Geological Map of the Russian Federation. Second edition. Scale 1:200,000. Ser. Altaisk. Sheet M-45-I (Soloneshnoe). Explanatory Note. FGUP Gorno-Altajskaya poiskovo-s"yomochnaya ekspediciya: Russia, 2001, Ed.: Shokalsky S.P.</mixed-citation></citation-alternatives></ref><ref id="cit67"><label>67</label><citation-alternatives><mixed-citation xml:lang="ru">Straus L.G., Gonzalez Morales M., Farrand W.R. et al. (2001). Sedimentological and stratigraphic observations in El Mirón, a late Quaternary cave site in the Cantabrian Cordillera, northern Spain. Geoarchaeol. Int. J. Vol. 16. No. 5. P. 603-630. https://doi.org/10.1002/gea.1012</mixed-citation><mixed-citation xml:lang="en">Straus L.G., Gonzalez Morales M., Farrand W.R. et al. (2001). Sedimentological and stratigraphic observations in El Mirón, a late Quaternary cave site in the Cantabrian Cordillera, northern Spain. Geoarchaeol. Int. J. Vol. 16. No. 5. P. 603-630. https://doi.org/10.1002/gea.1012</mixed-citation></citation-alternatives></ref><ref id="cit68"><label>68</label><citation-alternatives><mixed-citation xml:lang="ru">Theden-Ringl F., Gadd P. (2017) The application of X-ray fluorescence core scanning in multi-element analyses of a stratified archaeological cave deposit at Wee Jasper, Australia. J. Archaeol. Sci: Rep. Vol. 14. P. 241-251. https://doi.org/10.1016/j.jasrep.2017.05.038</mixed-citation><mixed-citation xml:lang="en">Theden-Ringl F., Gadd P. (2017) The application of X-ray fluorescence core scanning in multi-element analyses of a stratified archaeological cave deposit at Wee Jasper, Australia. J. Archaeol. Sci: Rep. Vol. 14. P. 241-251. https://doi.org/10.1016/j.jasrep.2017.05.038</mixed-citation></citation-alternatives></ref><ref id="cit69"><label>69</label><citation-alternatives><mixed-citation xml:lang="ru">Taylor S.R., McLennan S.M. (1985) The continental crust: its composition and evolution. Ox-ford: Blackwell (Publ.). 315 p.</mixed-citation><mixed-citation xml:lang="en">Taylor S.R., McLennan S.M. (1985) The continental crust: its composition and evolution. Ox-ford: Blackwell (Publ.). 315 p.</mixed-citation></citation-alternatives></ref><ref id="cit70"><label>70</label><citation-alternatives><mixed-citation xml:lang="ru">Tudela D.R., Araujo A.G., Tatumi S.H. et al. (2020) Preliminary evidence of prehistoric human activity by chemical analysis of sediments from Lapa Grande de Taquaraçu archaeological site using INAA. J. Radioanal. Nucl. Chem. Vol. 325. P. 725-736. https://doi.org/10.1007/s10967-020-07217-2</mixed-citation><mixed-citation xml:lang="en">Tudela D.R., Araujo A.G., Tatumi S.H. et al. (2020) Preliminary evidence of prehistoric human activity by chemical analysis of sediments from Lapa Grande de Taquaraçu archaeological site using INAA. J. Radioanal. Nucl. Chem. Vol. 325. P. 725-736. https://doi.org/10.1007/s10967-020-07217-2</mixed-citation></citation-alternatives></ref><ref id="cit71"><label>71</label><citation-alternatives><mixed-citation xml:lang="ru">Turk J., Turk M. (2010) Paleotemperature record in late pleistocene clastic sediments at Divje Babe 1 cave (Slovenia). J. Archaeol. Sci. Vol. 37. No. 12. P. 3269-3280. https://doi.org/10.1016/j.jas.2010.07.030</mixed-citation><mixed-citation xml:lang="en">Turk J., Turk M. (2010) Paleotemperature record in late pleistocene clastic sediments at Divje Babe 1 cave (Slovenia). J. Archaeol. Sci. Vol. 37. No. 12. P. 3269-3280. https://doi.org/10.1016/j.jas.2010.07.030</mixed-citation></citation-alternatives></ref><ref id="cit72"><label>72</label><citation-alternatives><mixed-citation xml:lang="ru">Ulyanov V.A., Kozlikin M.B., Shunkov M.V. (2015) Stratigraphic profile of the Pleistocene deposits in the Eastern Gallery of Denisova Cave (2015 excavation campaign). Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 21. P. 157-160 (in Russ.).</mixed-citation><mixed-citation xml:lang="en">Ulyanov V.A., Kozlikin M.B., Shunkov M.V. (2015) Stratigraphic profile of the Pleistocene deposits in the Eastern Gallery of Denisova Cave (2015 excavation campaign). Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 21. P. 157-160 (in Russ.).</mixed-citation></citation-alternatives></ref><ref id="cit73"><label>73</label><citation-alternatives><mixed-citation xml:lang="ru">Ulyanov V.A., Kozlikin M.B., Belousova N.E. et al. (2016) The structure of Pleistocene Deposits in the Main Chamber of Denisova Cave: The 2016 excavation profile. Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 22. P. 169-172 (in Russ.).</mixed-citation><mixed-citation xml:lang="en">Ulyanov V.A., Kozlikin M.B., Belousova N.E. et al. (2016) The structure of Pleistocene Deposits in the Main Chamber of Denisova Cave: The 2016 excavation profile. Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 22. P. 169-172 (in Russ.).</mixed-citation></citation-alternatives></ref><ref id="cit74"><label>74</label><citation-alternatives><mixed-citation xml:lang="ru">Ulyanov V.A., Shunkov M.V., Kozlikin M.B. (2022) 2022 study of Pleistocene deposits in the South Chamber of the Denisova Cave. Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 28. P. 317-321 (in Russ.). https://doi.org/10.17746/2658-6193.2022.28.0317-0321</mixed-citation><mixed-citation xml:lang="en">Ulyanov V.A., Shunkov M.V., Kozlikin M.B. (2022) 2022 study of Pleistocene deposits in the South Chamber of the Denisova Cave. Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 28. P. 317-321 (in Russ.). https://doi.org/10.17746/2658-6193.2022.28.0317-0321</mixed-citation></citation-alternatives></ref><ref id="cit75"><label>75</label><citation-alternatives><mixed-citation xml:lang="ru">Vasiliev S.K., Kozlikin M.B., Shunkov M.V. (2020) Faunal remains from the Pleistocene deposits in the Southern Chamber of Denisova Cave (evidence of 2019). Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 26. P. 37-42. (in Russ.). https://doi.org/10.17746/2658-6193.2020.26.037-042</mixed-citation><mixed-citation xml:lang="en">Vasiliev S.K., Kozlikin M.B., Shunkov M.V. (2020) Faunal remains from the Pleistocene deposits in the Southern Chamber of Denisova Cave (evidence of 2019). Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 26. P. 37-42. (in Russ.). https://doi.org/10.17746/2658-6193.2020.26.037-042</mixed-citation></citation-alternatives></ref><ref id="cit76"><label>76</label><citation-alternatives><mixed-citation xml:lang="ru">Vasiliev S.K., Shunkov M.V., Kozlikin M.B. (2021) Bone remains from the Pleistocene deposits in the South Chamber of Denisova Cave: new evidence. Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 28. P. 83-90. (in Russ.). https://doi.org/10.17746/2658-6193.2021.27.0083-0090</mixed-citation><mixed-citation xml:lang="en">Vasiliev S.K., Shunkov M.V., Kozlikin M.B. (2021) Bone remains from the Pleistocene deposits in the South Chamber of Denisova Cave: new evidence. Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 28. P. 83-90. (in Russ.). https://doi.org/10.17746/2658-6193.2021.27.0083-0090</mixed-citation></citation-alternatives></ref><ref id="cit77"><label>77</label><citation-alternatives><mixed-citation xml:lang="ru">Vasiliev S.K., Shunkov M.V., Kozlikin M.B. (2024) Theriofaunal remains from Pleistocene deposits in the South Chamber of Denisova Cave (2022–2024 collection). Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 30. P. 70-78. (in Russ.). https://doi.org/10.17746/2658-6193.2024.30.0070-0078</mixed-citation><mixed-citation xml:lang="en">Vasiliev S.K., Shunkov M.V., Kozlikin M.B. (2024) Theriofaunal remains from Pleistocene deposits in the South Chamber of Denisova Cave (2022–2024 collection). Problems of Archaeology, Ethnography, Anthropology of Siberia and Neighboring Territories. Vol. 30. P. 70-78. (in Russ.). https://doi.org/10.17746/2658-6193.2024.30.0070-0078</mixed-citation></citation-alternatives></ref><ref id="cit78"><label>78</label><citation-alternatives><mixed-citation xml:lang="ru">Vyncke K., Degryse P., Vassilieva E. et al. (2011) Identifying domestic functional areas. Chemical analysis of floor sediments at the Classical-Hellenistic settlement at Düzen Tepe (SW Turkey). J. Archaeological Sci. Vol. 38. No. 9. P. 2274-2292. https://doi.org/10.1016/j.jas.2011.03.034</mixed-citation><mixed-citation xml:lang="en">Vyncke K., Degryse P., Vassilieva E. et al. (2011) Identifying domestic functional areas. Chemical analysis of floor sediments at the Classical-Hellenistic settlement at Düzen Tepe (SW Turkey). J. Archaeological Sci. Vol. 38. No. 9. P. 2274-2292. https://doi.org/10.1016/j.jas.2011.03.034</mixed-citation></citation-alternatives></ref><ref id="cit79"><label>79</label><citation-alternatives><mixed-citation xml:lang="ru">Warr L.N. (2021). IMA–CNMNC approved mineral symbols. Mineral. Mag. Vol. 85. No. 3. P. 291–320. https://doi.org/10.1180/mgm.2021.43</mixed-citation><mixed-citation xml:lang="en">Warr L.N. (2021). IMA–CNMNC approved mineral symbols. Mineral. Mag. Vol. 85. No. 3. P. 291–320. https://doi.org/10.1180/mgm.2021.43</mixed-citation></citation-alternatives></ref><ref id="cit80"><label>80</label><citation-alternatives><mixed-citation xml:lang="ru">White W.B. (2007) Cave sediments and paleoclimate. J. Cave Karst Stud. Vol. 69. No. 1. P.76–93</mixed-citation><mixed-citation xml:lang="en">White W.B. (2007) Cave sediments and paleoclimate. J. Cave Karst Stud. Vol. 69. No. 1. P.76–93</mixed-citation></citation-alternatives></ref><ref id="cit81"><label>81</label><citation-alternatives><mixed-citation xml:lang="ru">White W.B. (2019). Speleothems. In: White W.B., Culver D.C., Pipan T. Encyclopedia of Caves. Elsevier Inc. P. 1006-1017. https://doi.org/10.1016/B978-0-12-814124-3.00117-5</mixed-citation><mixed-citation xml:lang="en">White W.B. (2019). Speleothems. In: White W.B., Culver D.C., Pipan T. Encyclopedia of Caves. Elsevier Inc. P. 1006-1017. https://doi.org/10.1016/B978-0-12-814124-3.00117-5</mixed-citation></citation-alternatives></ref><ref id="cit82"><label>82</label><citation-alternatives><mixed-citation xml:lang="ru">Wilson C.A., Davidson D.A., Cresser M.S. (2008) Multi-element soil analysis: an assessment of its potential as an aid to archaeological interpretation. J. Archaeol. Sci. Vol. 35. No. 2. P. 412-424. https://doi.org/10.1016/j.jas.2007.04.006</mixed-citation><mixed-citation xml:lang="en">Wilson C.A., Davidson D.A., Cresser M.S. (2008) Multi-element soil analysis: an assessment of its potential as an aid to archaeological interpretation. J. Archaeol. Sci. Vol. 35. No. 2. P. 412-424. https://doi.org/10.1016/j.jas.2007.04.006</mixed-citation></citation-alternatives></ref><ref id="cit83"><label>83</label><citation-alternatives><mixed-citation xml:lang="ru">Yudovich Ya.E., Ketris M.P. (2011) Geochemical indicators of lithogenesis (lithologic geochemistry). Syktyvkar: Geoprint (Publ.), 742 p. (in Russ.)</mixed-citation><mixed-citation xml:lang="en">Yudovich Ya.E., Ketris M.P. (2011) Geochemical indicators of lithogenesis (lithologic geochemistry). Syktyvkar: Geoprint (Publ.), 742 p. (in Russ.)</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
